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A striking advantageous asset of this new method could be the use of more reactive aryl sulfilimines rather than the matching harzadous azides. Different catalysts and divergent light sources were tested. The effect scope is broad together with product yield is typically high. A competent gram scale synthesis of Clausine C shows the applicability and scalability of the brand new method. © 2020 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim.INTRODUCTION A competent ch