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Mixed relationships occur in southern Europe. These special patterns are strongly associated with specific natural factors, especially the extensive occurrence of quartz-rich soil in the central-eastern part of Europe. Anthropogenic inputs may have also played a role in the mixed southern European areas. The GWR technique is powerful and effective for revealing spatially varying relationships at the local level. Thus, it provides a new way to further explore the related influencing factors on the TOC and pH spatial distribution.Nowadays