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The current study presents a direct CF2H radical addition to C[double bond, length as m-dash]N bonds predicated on the photocatalytic activation of commercially available zinc difluoromethanesulfinate. The mild conditions in place lead to impressive structural diversity, as quinoxalinones and dibenzazepines, among others, are successfully functionalized.Correction for 'Isomer-specific cryogenic ion vibrational spectroscopy of the D2 tagged Cs+(HNO3)(H2O)n=0-2 complexes ion-driven enhancement of the acidic H-bond to water' by Sayoni Mitra