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P25 TiO2 photoanodes are used to photo-oxidise water in two different acids, 0.5 M H2SO4 and 1 M HClO4. In the former acid, the linear sweep voltammogram, LSV, appears to exhibit two photocurrent waves, whilst only one in the latter. In 0.5 M H2SO4, the recorded LSV coupled with a low faradaic efficiency (0.58) for the photooxidation of water to O2, fO2, and a significant level of persulfate, fS2O8 = 0.12, shows that the electrochemical kinetics are not simply those for water oxidation. In 1 M HClO4, the LSV coupled with a high fO2 valu