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The introduced N-O bond reconstructs the electron "push-pull" system of heterocyclic scaffolds and dramatically gets better their photophysical properties by red-shifting the spectra and enhancing the Stokes shift. Meanwhile, the heterocyclic N-O bond also allows a function associated with the fluorescence switch. It may turn on the fluorescence of pyridine while increasing the fluorescence of quinoline and, conversely, reduce steadily the fluorescence of acridines and resorufin. As
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