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With a rise in Ge content in the crystals, new consumption bands, corresponding to your vibrations of OGeO when you look at the GeO4 tetrahedra (670, 930, 1010, 2125 cm-1), appeared, and the intensities for the absorption bands of OSiO when you look at the SiO4 tetrahedra (263, 695, 2137, doublet at 2326 and 2333, 2499, 2599, 2673 cm-1) diminished. The shifts into the consumption groups at 354, 511, 2499 and 2673 cm-1 to reduce wavenumbers linearly is dependent upon the Ge content and so a
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