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This work proposes a general strategy to enhance PE responses of Schottky contacts, which may advance the design of LSPR-related PE systems.In spite of the recent progress made in organic electrode materials, high-performance candidates are still lacking, especially when taking affordability into account. Herein, we report a novel polymeric lithium salt, namely dilithium salt of poly(2,5-dihydroxy-1,4-benzoquinone-3,6-methylene) (Li2PDBM), which can be easily synthesized by phenol-formaldehyde condensation, followed by lithiation in LiO