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Colloids, such as natural particulate matter and microplastics, can play a significant role in the fate and transport of organic contaminants. Specifically, these small nano-to micron-sized particles provide large surface area; thus, particle-aqueous interfacial chemistry becomes significant. In this work, we present an experimental investigation of interfacial photokinetics of malachite green cation (MG+) adsorbed at the surface of polystyrene carboxyl (PSC) microspheres suspended in aqueous solution. Second harmonic generation (SHG), an