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The pronounced electrical output and Cu2+ reduction efficiencies can be realized through the synergistic cooperation between the bioanode and BiFeO3/ZnO photocathode in the MFC. Furthermore, the developed BiFeO3/ZnO composite presented a good stability and reusability of photoelectrocatalytic activity up to five cyclic runs.Activating peroxides to produce active substances is the key to advanced oxidation processes (AOPs), but this usually requires energy or is accompanied by additional contaminants. In this study, diclofenac (DCF) wa