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Developing new coating modification technology of aluminum nitride (AlN) powder for higher hydrolysis resistance is the key to prepare high-performance AlN ceramic substrate with water-based wet process in the future. In the this paper, The poly(vinyl pyrrolidone)-b-poly(Styrene/Itaconic anhydride) (PVP-b-P(St/ITA))block copolymer with PVP as the independent chain segment was designed and synthesized through reversible addition fragmentation chain transfer (RAFT) polymerization, which was used for the study on coating modification, hydr