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This study provides comprehensive and insightful information on the roles of Fe(V)/Fe(IV) during EOC oxidation by Fe(VI).The reactivity of garnet solid electrolytes toward humid air hinders their practical application despite their attractive, superior properties such as high Li+ conductivity and wide electrochemical window. Sealing garnets with organic solvents can not only prevent them from reacting with humid air but also render them compatible with other processing technologies. Therefore, the chemical and structural stability of garn
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