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In line with the results, TYBI displays better inhibition performance than FYBI. Also, the high-resolution XPS and quantum calculation results expose that the S-heterocycle indole (TYBI) can easily give electrons towards the vacant d orbital of Cu and develop better quality, hydrophobic, and anti-corrosive SAMs as compared to O-heterocycle indole (FYBI). The inhibited deterioration is accomplished by inhibiting the generation of Cu2+. This organized resea