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1 to 16 ppm. The limit of detection was calculated to be as low as 8.75 ppb (3σ/S). In addition, the successful detection of glyphosate in real samples with satisfactory recoveries exhibited a practical application of the CD/Fe3+ nanoprobe in food safety and environmental monitoring.A combination of pillar[5]-bis-trithiacrown (L) and mercury(ii) halides afforded a monomer complex (Cl--form), a 1-D coordination polymer (Br--form) and a supramolecular ion-triplet complex [(I·Hg·I)@L] (I--form). In the ion-triplet complex, the host encapsulates the (I-