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The integration of polymer chains with organolead halide perovskite (MAPbI3) films, leading to enhanced stability and electro-optical performance, is critically affected by the molecular weight of chains. The molecular weight determines the mobility and volume of the chains, which affects the crystallization kinetics and, hence, perovskite grain size. The insulating nature of the chains is another critical factor that affects both ion migration and conduction of electronic charge. The combined effect of these factors leads to optimal p
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