https://sp600125inhibitor.com/....detection-of-two-qtl
© 2020 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim.Starting from easily obtainable o-diazoacyl-substituted arene carboxylates, scaffolds because of the 5,9-epoxycyclohepta[b]pyran-2(3H)-one core were gotten by cooperative Rh(II), Lewis and Brønsted acid catalysis. Four brand new bonds, three useful groups (lactone, ketal, and alcohol) and four contiguous stereocenters are formed during this regio- and diastereoselective process in a single synthetic action. Intensive optimization and mechanistic s
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