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Self-assembled frameworks of phenolic/LEL combinations mediated by hydrogen bonding interaction were decided by FTIR and SAXS analyses. Through thermal curing and carbonization treatments, huge mesoporous carbons (50 nm) with a cylindrical framework and high surface area (600 m2/g) were acquired since the OH devices of phenolics would rather interact with PEO block rather than PLA block, as determined by FTIR spectroscopy. Moreover, higher CO2 capture and great power storage performance were obs