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To fabricate antibacterial activity and simultaneous strengthened and toughened carboxylated nitrile butadiene rubber (XNBR) composites, starch was oxidized by H2O2 to achieve oxidized starch (OST) with different carboxyl content, meanwhile, ZnO were utilized to promote the in-situ interfacial reaction for improving compatibility of starch and XNBR. The formation of ionic cross-link networks and "Zinc-carboxylate polymers" in the XNBR/OST/ZnO composites were confirmed by FT-IR, XRD, XPS, SEM-EDS and TEM. Interestingly, because of the c
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