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This analysis summarizes the advances in heteroarene customization via reactions of in situ formed (hetero)arene cation radicals, including 2010 to 2020.Developing hydrogels with ideal properties for specific programs is challenging since many of the properties, such as for instance toughness, tightness, swelling or deformability, tend to be interrelated. The enhancement of one home usually comes during the cost of another. So that you can decouple the interdependence between these properties and to extend the nu