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nism for oxidation of the heterochiral cerium REMB frameworks, reiterating the importance of the formation of inner-sphere complexes in the oxidation chemistry of cerium. There are many different avenues for both organic and inorganic investigation of Shibasaki's REMB framework, and our works have demonstrated the richness of the structural chemistry and properties of this framework that inform mechanism and properties of these privileged catalysts.Chlorophyll special pairs in photosynthetic reaction centers function