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001). CONCLUSIONS Complementary education of French dentists in the domain of caries management appears necessary regarding current recommendations. This article is protected by copyright. All rights reserved.Self-sustained NiI/III cycles are established as a potentially general paradigm in photoredox Ni-catalyzed carbon-heteroatom cross-coupling reactions through a strategy that allows us to recapitulate photoredox-like reactivity in the absence of light across a wide range of substrates in the amination, etherification, and esterification of aryl bromides
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