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the THF molecules in 10a,c and dimerization. Heating solutions of 10a,c at 60 °C triggers ligand rearrangement to give phosphinimine-amidinato compounds [Liκ2-N,N'-(NR)C(NDipp)(PPh2NR)(THF)2] (12a,c). We also propose a mechanism for the ligand rearrangement reaction from 10a to give 12a, supported by DFT calculations, which fits nicely with our experimental results. It essentially involves a carbodiimide deinsertion reaction followed by a [3 + 2] cycloaddition between the resulting lithium phosphino-amide and the carbodiimide.Longisgluci
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