https://www.selleckchem.com/pr....oducts/acalabrutinib
The iridium tetrahydride complex Cp*IrH4 reacts with a range of isobutylaluminum derivatives of general formula Al(iBu)OAr)3-x (x = 1, 2) to give the unusual iridium aluminum species [Cp*IrH3Al(iBu)(OAr)] (1) via a reductive elimination route. The Lewis acidity of the Al atom in complex 1 is confirmed by the coordination of pyridine, leading to the adduct [Cp*IrH3Al(iBu)(OAr)(Py)] (2). Spectroscopic, crystallographic, and computational data support the description of these heterobimetallic complexes 1 and 2 as featuring strongly
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