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The big (H2O)100, (H2O)120 and (H2O)140 clusters complete the hydrogen bonding system of this cage with ideal and regular tiling of this do-, tetra-decahedron and hexa-decahedron, respectively. This study is corroborated by an investigation of thick water groups as much as the (H2O)123 one, being highly in keeping with experimental information on ice concerning the electronic and zero-point energies for aggregate development at 0 K and enthalpy and entropy at 273 K. The cavity creation profoundly alters the direct