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These characteristics lay a foundation for further investigation about the catalytic activity of the hollow MnFeO oxide nanomaterials and make it show broad prospects in the field of biosensing and catalysis.Elastic biomass aerogels have attracted widespread attention but are seriously hindered by environmentally unfriendly cross-linkers and fire hazards for functional applications. This study outlines the fabrication of a fully bio-based, low fire-hazard and superelastic aerogel without any cross-linkers for excellent thermal insulat