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The desired photoelectrochemical performance can be achieved by temperature regulation, but the nature for this improvement remains a controversial topic. Herein, we employed BiVO4/CoOx as a typical model system, and explored the fate of photogenerated holes at the different interfaces among BiVO4/CoOx/electrolyte by means of intensity modulated photocurrent spectroscopy (IMPS), scanning photoelectrochemical microscopy (SPECM) and traditional electrocatalysis characterization methods. Systematic quantitative analysis of the kinetics of pho
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