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The first electrochemical dehydrogenative C-S bond formation leading to thienoacene derivatives is described. Several thienoacene derivatives were synthesized via dehydrogenative C-H/S-H coupling. The addition of nBu4 NBr, which catalytically promoted the reaction as a halogen mediator, was essential. © 2020 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim.When faced with changing contingencies, animals can use memory to flexibly guide actions, engaging both frontal and temporal lobe brain structures. Damage to the hippocampus (HPC) impair