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The advanced rechargeable batteries have been upgraded by the production of free-standing electrodes through electrospinning technology. This study aimed to introduce a novel hybrid composition to design a free-standing carbon nanofiber (CNF) based anode by the addition of iron acetylacetonate Fe(AcAc)3 as active material and TEOS(tetraethoxysilane)/APTES(aminopropyl triethoxysilane) as an additive for Li-ion batteries. Polyacrylonitrile(PAN) was used as the polymer matrix in the spin dope, and the inclusion of Fe(AcAc)3 and TEOS/APTES re