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The layered lithium-metal oxides are promising cathode materials for Li-ion batteries. Nevertheless, their widespread applications have been limited by the high cost, complex process, and poor stability resulting from the Ni2+/Li+ mixing. Hence, we have developed a facile one-spot method combining glucose and urea to form a deep eutectic solvent, which could lead to the homogeneous distribution and uniform mixing of transition-metal ions at the atomic level. LiNi0.5Co0.2Mn0.3O2 (NCM523) polyhedron with high homogeneity could be obtained