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Compared with Cu-SSZ-13, the catalytic activity and hydrothermal security of this Cu-SSZ-13@meso-MOx were greatly improved. The marketing effectation of meso-MOx layer on the catalytic activity of Cu-SSZ-13 is mainly attribute towards the existence of both microporous and mesoporous structures, the synthesis of more vigorous isolated Cu2+ ions and more L-acid internet sites, additionally the synergistic result between Cu-SSZ-13