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Our findings on immune cell-specific DNA nanostructures may be applied for vaccine development, immunomodulatory therapy to suppress septic shock, or the targeting of bioactive substances to immune cells.For years, the space charge layer formation in Li-conducting solid electrolytes and its relevance to so-called all solid-state batteries have been controversially discussed from experimental and theoretical perspectives. In this work, we observe the phenomenon of space charge layer formation using impedance spectroscopy at different ele