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5%. Our electrochemical measurements on individual Ag nanoprisms with various edge-to-basal plane ratios and the Ag superstructures led to the identification of the edge ribs as the active sites thanks to the ≈400 mV decrease in the onset potential compared to that of the Ag (111) basal planes and a turnover frequency of 9.2 × 10-3 ± 1.9 × 10-3 s-1 at 0 V overpotential.The dynamics of complex ordering systems with active rotational degrees of freedom exemplified by protein self-assembly is explored using a machine learning workflow that