https://www.selleckchem.com/products/corn-oil.html
An efficient tandem hydrosilylation of CO2, which uses a combination of a simple, homoleptic lanthanum aryloxide and B(C6F5)3, was performed. Use of a less sterically hindered silane led to an exclusive reduction of CO2 to CH4, with a turnover frequency of up to 6000 h-1 at room temperature. The catalytic system is robust, and 19 400 turnovers could be achieved with 0.005 mol% loading of lanthanum. The reaction outcome depended highly on the nature of the silane reductant used. Selective production of the formaldehyde equivalent, i.e.,
Like
Comment
Share
