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Two FeII8L12 cubic metal-organic cages were constructed with semi-rigid ligands and they further self-assembled into supramolecular assemblies with three different porous cavities. The supramolecular assemblies showed synergistic adsorption of I2 and TTF, and their solid state spin-crossover behaviors were influenced by the adsorbed guest molecules.Polymeric carbon nitrides (PCNs) are promising photocatalysts and electrocatalysts for water oxidation, as they are environmentally benign materials with an adjustable structure and facilely