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The TWCCSN2 values derived from TWIMS measurements are in excellent agreement with those determined by DTIMS ( less then 2% relative difference), demonstrating the effectiveness of the proposed calibration scheme. Moreover, we used theoretical methods to predict the structures and CCS values of the anions considered. These predictions are in good agreement with the experimental results and give further insight into the trends governing the assembly of tetraorganylborate, cuprate, and argentate oligomers.Li2S-based Li-S batteries are t