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1 eV, but the T1 energy is hardly changed. The obtained reduction of ΔEST is crucial to effectively suppress triplet recombination and acquire small exciton dissociation driving force. Thus, end-group π-π stacking is an effective way to achieve both small energy loss and efficient light absorption for high-efficiency organic photovoltaics. © 2020 WILEY-VCH Verlag GmbH Co. KGaA, Weinheim.The energetically viable fabrication of stable and highly efficient solid acid catalysts is one of the key steps in the large-scale transformatio