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The uniform separation between resonances and the dynamics that show excitons can only relax to the next-lowest state are consistent with a vibronic progression caused by a vibrational mode on the cation. These results demonstrate that simple changes to the cation can be used to tailor the properties and dynamics of the confined excitons without directly modifying the inorganic framework.The alteration of modified amino acid (MAA) profiles in biological samples is related to important cellular, physiological, and pathological processes.