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The effects of cathode material (aluminum, stainless steel), total current density and anode surface area (3.3-30 mA cm-2 and 12-36 cm2, respectively) were investigated, and lead to NH4+-N percentage removals of between 25% (10 mA cm-2, 12 cm2) and 100% (30 mA cm-2, 24 cm2) for an initial NH4+-N concentration of 10 mg L-1. The optimum EC (20 mA cm-2, natural initial pH 7.5-7.8) and EO parameters (30 mA cm-2, 24 cm2 surface area anode, Al cathode) were combined into a hybrid system to treat two real nitrate-polluted groundwaters with initi