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In contrast, the synthesis conditions of Ce(iv)-MOFs were only recently (2015) established. These lead selectively to hexanuclear Ce-O clusters that are well-known for Zr-MOFs and therefore very similar structural and isoreticluar chemistry is found. Hence Ce(iv)-MOFs exhibit often high porosity, while only a few porous Ce(iii)-MOFs have been described. Some of these show structural flexibility which makes them interesting for separation processes. For Ce(iv)-MOFs the redox properties are most relevant. Thus, they are intensively discus
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