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In crystallography, ligand distortions occur in ThL2 complexes, and TMBiDA distorts more than TMPhenDA does; the Th-O and Th-N bonds involving TMBiPDA are slightly shorter than those involving TMPhenDA.The design of active photocathodes for the hydrogen evolution reaction (HER) is a crucial step in the development of dye-sensitized photoelectrochemical cells (DS-PECs) aimed at solar-assisted water splitting. In the present work, we report on the use of orange CdTexS1-x quantum dots (QDs) with an average diameter of ca. 3.5 nm, featuring d