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This article used O3 to mimic the oxidizing environment in the Li-ion battery by providing active atomic oxygen. It provided insights into the chemically sensitized gas-phase low-temperature chemistry of DEC and explained the mechanism of battery degradation involving the low-temperature oxidation at the electrolyte solvent and the cathode interface from 400 to 500 K.Electrochemical capacitors (ECs) have emerged as reliable and fast-charging electrochemical energy storage devices that offer high power densities. Their use is still limit