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Cu-based ternary alloy nanocrystals have emerged for extensive applications in solar cells, light-emitting devices (LEDs), and photoelectric detectors because of their low-toxicity, tunable band gaps, and large absorption coefficients. It is still an enormous challenge that regulating optical and electrical properties through changing their compositions and shapes in alloy nanocrystals. Herein, we present a facile method to synthesize CuCdS alloy nanocrystals (NCs) with tunable compositions and shapes at relatively low temperature. Diff