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Consequently, the gel electrolyte can cycle for more than 500 h under a high current density of 3 mA cm-2 on dendrite inhibition performance, and when assembled with LiFePO4 as a cathode, the battery demonstrates a reversible specific capacity as high as 70 mAh g-1 under a high current density of 5 C after 300 cycles. The rational designed solvophilic/solvophobic zwitterionic elastomers provide a guidance for engineering quasi-solid state electrolytes of different solvents with broad applications on flexible devices.In this research, the