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Herein, we describe a series of three sterically congested nitrogenated benzodipentaphenes, one of which shows a highly distorted aromatic backbone with an unprecedented double π-expanded helicene structure.Colloidal semiconductor nanocrystals (NCs) are promising components in various optoelectronic and photocatalytic devices; however, the mechanism of energy transport in these materials remains to be further understood. Here, we investigate the distance dependence of the electronic interactions between CsPbBr3 nanocubes and CdSe nanoplatel