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The crystallization behaviours of amorphous poly(vinylidene fluoride) (PVDF) nanocompositesmodified with two different kinds of molybdenum disulfide (MoS₂) at different filler loadings were investigated in detail in this work. The crystallinity, melting temperature and crystallization temperature of the PVDF/MoS₂ nanocomposites were transformed from α-phase to β-phase with the addition of MoS₂, MoS₂-COOH and MoS₂-NH₂. During isothermal cold crystallization, the overall crystallization rate of PVDF was slowed with increased MoS₂ loading
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