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The structure-directing role of the hydrogen bonded counterions in these nanotubular species, either NH4+ located within the nanotubule cavity or [Cen)3]3+ located outside, is discussed. Emission spectra in the solid state display the usual vibronic fine structure for 1 and 4, while uranyl emission is quenched in 3.Exogenous electron mediators (EMs) can facilitate extracellular electron transfer (EET) via electron shuttling processes, but it is still unclear whether and how biofilm formation is affected by the presence of EMs. Here, th