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A self-supporting catalyst consisting of 1D/2D vertical molybdenum disulfide@titanium dioxide/nitrogen-doped carbon nanofiber (MoS2@TiO2/NCNFs) was prepared and tested. It showed efficient hydrogen peroxide (H2O2) decomposition to generate hydroxyl radical (OH) and degradation of various pollutants under solar irradiation. The contribution of the increase in MoS2 edges for decomposing H2O2 was 0.0698 min-1. That is 9.83 times the rate of the original MoS2 edges resulting from the vertical structure. Specially, the catalyst degraded vario