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Importantly, the glycerol-water solvent bestowed the distinct anti-freezing (-30 °C) and anti-dehydration performances on the PTOs. Accordingly, the materials could serve as promising rewritable devices for high-resolution and long-term data storage/encryption. Moreover, on-demand PTO windows integrating UV-prevention and solar energy regulation with Tlum (92.96%) and ΔTsol (46.02%) could create comfortable and healthy environments for occupants. This work offers a new design strategy for low-cost, environmentally stable smart optical de