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The calcined samples were characterized by XRD, SEM, TEM, AFM, BET, and DLS techniques. The catalytic application of this emulsions stabilized by MgO ended up being examined when it comes to Knoevenagel condensation result of benzaldehyde and its derivatives with malononitrile. All the reactions had been done at an ambient heat (30 °C) under fixed conditions without stirring. Both the emulsion-stabilizing capability plus the catalytic activity of MgO had been found is afflicted with the technique of prepar