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e., palaeoentomology, vibrational spectroscopy, neutron tomography, etc.).Qualitative and quantitative Raman and infrared measurements on sodium nitrate (NaNO3) solutions have been carried out over a wide concentration range (5.56 × 10-6-7.946 mol/L) in water and heavy water. The Raman spectra were measured from 4000 cm-1 to low wavenumbers at 45 cm-1. Band fit analysis on the profile of the 1047 cm-1 band, ν1(a 1 ' ) NO 3 - measured at high resolution at 0.90 cm-1 produced a small contribution at 1027 cm-1 of the isotopomer N16O218O(