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Developing room-temperature phosphorescence (RTP) materials with color-tunability performance in an aqueous environment is crucial for application in optoelectronic areas to a higher stage, such as multicolor display, visual detection of external stimulus, and high-level information anticounterfeiting, but still faces a formidable challenge. Herein, we propose an efficient design strategy to develop excitation wavelength-responsive RTP supramolecular co-assembly systems of a simple benzoic acid derivative and Laponite (Lap) clay nanopla